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Technical Specification: Buffers & Solutions

1. Product Overview

Solarbio buffers and solutions are manufactured for molecular biology, cell culture, and biochemical applications. Each solution is prepared at ISO 9001:2015 certified facilities using USP/EP-grade raw materials and USP-grade water (18.2 MΩ·cm, <5 ppb TOC). All buffers are 0.1 µm filtered, DNase/RNase-free, and tested for endotoxin content.

2. Product Range

Product SKU Concentration Package Size Key Feature
PBS (Phosphate Buffered Saline) P1010 1×, pH 7.4 500 mL, 1000 mL Cell culture grade, Ca²⁺/Mg²⁺-free
10× PBS P1020 10× concentrate 500 mL Dilute to 1× with sterile water
TAE (Tris-Acetate-EDTA) T1060 50× concentrate 500 mL, 1000 mL DNA electrophoresis, 40 mM Tris-acetate
TBE (Tris-Borate-EDTA) T1050 10× concentrate 500 mL Higher resolution for small DNA fragments
20× SSC S1030 20× concentrate 500 mL Southern/Northern blotting, 3 M NaCl
10× Tris Buffered Saline (TBS) T1080 10×, pH 7.4 500 mL Western blot wash buffer
1 M Tris-HCl pH 8.0 T1120 1 M 500 mL Molecular biology grade
1 M Tris-HCl pH 7.4 T1150 1 M 500 mL Biochemical assay buffer
1 M HEPES pH 7.5 H1080 1 M 500 mL Cell culture buffer

3. Complete Formulation Tables

3.1 PBS (1×, pH 7.4) — SKU P1010

Component mM (1×) MW (g/mol) g/L Role
NaCl 137 58.44 8.006 Osmotic balance
KCl 2.7 74.55 0.201 Ionic balance
Na₂HPO₄ 8.0 141.96 1.136 Buffering component
KH₂PO₄ 2.0 136.09 0.272 Buffering component

Target values: pH 7.4 ± 0.1 at 25°C; Osmolality 280–315 mOsm/kg; Conductivity 15.0–16.5 mS/cm.

3.2 TAE (50× Stock → 1× Working)

Component mM (1×) mM (50×) MW (g/mol) g/L (50×) Role
Tris base 40 2000 121.14 242.28 Buffering agent
Acetic acid 60.05 57.1 mL/L (glacial) Counter-ion
EDTA 1 50 372.24 (Na₂) 18.61 Chelating agent

Target: 1× TAE pH 8.3 ± 0.1 at 25°C.

3.3 TBE (10× Stock → 1× Working)

Component mM (1×) mM (10×) MW (g/mol) g/L (10×) Role
Tris base 89 890 121.14 108.0 Buffering agent
Boric acid 89 890 61.83 55.0 Counter-ion
EDTA 2 20 372.24 (Na₂) 7.44 Chelating agent

Target: 1× TBE pH 8.3 ± 0.1 at 25°C.

3.4 SSC (20× Stock → 1× Working)

Component mM (20×) g/L (20×) Role
NaCl 3000 175.3 Ionic strength for hybridization
Na₃·citrate·2H₂O 300 88.2 Buffering and Ca²⁺ chelation

Target: 20× SSC pH 7.0 ± 0.2 at 25°C.

3.5 TBS (10× Stock) — SKU T1080

Component mM (10×) g/L (10×) Role
Tris base 200 24.23 Buffering agent
NaCl 1370 80.06 Ionic strength

Target: 10× TBS pH 7.4 ± 0.1 at 25°C.

3.6 Tris-HCl (1 M) — SKUs T1120 (pH 8.0), T1150 (pH 7.4)

Component Concentration MW (g/mol) g/L
Tris base 1 M 121.14 121.14
HCl Titrate to target pH 36.46 Variable

3.7 HEPES (1 M, pH 7.5) — SKU H1080

Component Concentration MW (g/mol) g/L
HEPES (free acid) 1 M 238.30 238.30
NaOH Titrate to pH 7.5 40.00 Variable

4. pH vs Temperature Coefficient

Buffer pH values shift with temperature — a critical parameter for reproducible results.

Buffer ΔpH/°C pH at 4°C pH at 25°C pH at 37°C
Tris-HCl (nominal pH 8.0 at 25°C) −0.028 8.59 8.00 7.66
Tris-HCl (nominal pH 7.4 at 25°C) −0.028 7.99 7.40 7.06
HEPES −0.014 7.64 7.30 7.09
PBS −0.0028 7.42 7.40 7.38
Phosphate buffer (50 mM) −0.0028 7.00 6.97

Note: Tris buffers exhibit a large negative coefficient. A Tris buffer prepared at pH 8.0 at 25°C will read pH 8.59 at 4°C and pH 7.66 at 37°C. Always adjust pH at the intended working temperature. HEPES has half the temperature sensitivity of Tris and is preferred for cell culture work at 37°C.

5. Storage After Opening — Stability Periods

Product Unopened Stability (RT) After Opening (RT) After Opening (2–8°C) Notes
PBS, 1× 24 months 6 months 12 months Discard if turbid
PBS, 10× 24 months 12 months 24 months Concentrate more resistant
TAE, 50× 24 months 6 months 12 months EDTA may precipitate if chilled
TBE, 10× 24 months 6 months 6 months Borate may crystallize at 4°C
SSC, 20× 24 months 12 months 18 months Stable concentrate
TBS, 10× 24 months 12 months 24 months Stable concentrate
TBS-T (with Tween 20) 18 months 3 months 6 months Tween 20 may hydrolyze over time
1 M Tris-HCl 24 months 12 months 12 months Discard if precipitate forms
1 M HEPES 24 months 12 months 18 months Stable; light-sensitive over long storage

6. Application-Specific Guidance

Buffer Recommended For Not Recommended For Reason
TAE Standard agarose gel electrophoresis (0.7–2% agarose); DNA recovery from gels High-resolution separation of <300 bp fragments Lower buffering capacity than TBE; bands blur in long runs
TBE High-resolution gel electrophoresis; small DNA fragments (100–500 bp); native PAGE Preparative gel purification Borate inhibits ligation; remove by ethanol precipitation
PBS Cell washing, immunofluorescence, immunohistochemistry, ELISA washing Long-term cell incubation (lacks nutrients, Ca²⁺, Mg²⁺) Only for wash steps; use DMEM/RPMI for incubation
SSC Southern blot, Northern blot, colony hybridization Cell culture High salt interferes with biological systems
TBS Western blot wash, ELISA, protein purification (ion exchange) Immunofluorescence (may cause background) Use PBS for IF
Tris-HCl Biochemical enzyme assays, DNA/RNA solubilization, protein purification Cell culture medium preparation (low buffering at 37°C) Use HEPES or carbonate for culture
HEPES Cell culture medium (37°C), live-cell imaging, electrophysiology Electrophoresis running buffers Poor conductivity for gels

7. Buffer Selection Guide by Downstream Application

Downstream Application Recommended Buffer Alternative Buffer Key Selection Criteria
DNA agarose gel electrophoresis 1× TAE 0.5× TBE TAE for DNA recovery; TBE for fine resolution
Native PAGE 1× TBE 1× TAE TBE gives sharper bands in polyacrylamide
Western blot — transfer 1× Transfer buffer (Tris-glycine-SDS) 1× TBS Dedicated transfer buffer required
Western blot — wash 1× TBS-T 1× PBS-T TBS-T preferred for reduced background
ELISA — coating 50 mM carbonate-bicarbonate pH 9.6 1× PBS Carbonate for alkaline pH coating
ELISA — wash 1× PBS-T 1× TBS-T PBS-T is standard for ELISA
Immunofluorescence 1× PBS 1× TBS PBS standard; TBS if phosphate interferes
Cell culture medium HEPES-buffered DMEM/RPMI CO₂-bicarbonate system HEPES for atmospheric CO₂ experiments
Southern/Northern blot 20× SSC 20× SSPE SSC is more widely established
Chromatin immunoprecipitation (ChIP) ChIP lysis buffer + 1× PBS Use dedicated shearing buffers
Protein purification (IMAC) 50 mM Tris, 300 mM NaCl, pH 8.0 50 mM phosphate, 300 mM NaCl Tris for imidazole gradient elution
Protein purification (IEX) 20 mM Tris (anion) or 50 mM MES (cation) Match buffer to pI of target protein

8. Quality Release Specifications

Every lot of Solarbio buffer and solution undergoes quantitative release testing against the following specifications.

Parameter PBS (1×) TAE (50×) TBE (10×) Tris-HCl (1 M) HEPES (1 M) Test Method
pH at 25°C 7.40 ± 0.10 8.30 ± 0.10 8.30 ± 0.10 8.00 ± 0.05 / 7.40 ± 0.05 7.50 ± 0.05 Three-point calibrated pH meter
Conductivity 15.8 ± 0.8 mS/cm Conductivity meter, ±2%
Osmolality 298 ± 15 mOsm/kg Freezing point depression
Absorbance 260 nm <0.05 AU <0.10 AU <0.10 AU <0.05 AU <0.05 AU UV-Vis, 1 cm path
Absorbance 280 nm <0.05 AU <0.10 AU <0.10 AU <0.05 AU <0.05 AU UV-Vis, 1 cm path
Endotoxin <0.5 EU/mL <1.0 EU/mL <1.0 EU/mL <0.5 EU/mL <0.5 EU/mL LAL chromogenic (USP <85>)
DNase Not detectable Not detectable Not detectable Not detectable Not detectable Fluorogenic substrate assay
RNase Not detectable Not detectable Not detectable Not detectable Not detectable Fluorogenic substrate assay
Protease Not detectable Not detectable Not detectable Not detectable Not detectable Resorufin-casein assay
Sterility 0.1 µm filtered 0.1 µm filtered 0.1 µm filtered 0.1 µm filtered 0.1 µm filtered Membrane filtration, 14-day

Acceptance criteria: A lot passes only when all parameters fall within specification. Failed parameters trigger a formal OOS investigation and lot rejection.

9. Common Mistakes and Troubleshooting

Problem Likely Cause Solution
White precipitate in PBS after refrigeration K⁺/phosphate crystallization at low temperature; concentration error Warm to RT and swirl to redissolve. Recheck osmolality before use.
pH drift >0.2 units after 24 h Wrong storage temperature; container not sealed; CO₂ absorption (PBS/TBS) Always seal tightly. For alkaline Tris buffers, minimize exposure to air. pH can drift 0.1–0.3 units over days if left open.
TAE buffer overheats during electrophoresis EDTA concentration too low; insufficient buffering capacity Use fresh 1× TAE. Do not reuse running buffer more than 2–3 times. For long (>2 h) runs, recirculate or use 1.5× TAE.
No bands visible on gel (TBE) Borate inhibition of enzymatic downstream steps Borate can inhibit ligation, restriction digestion, and sequencing. Ethanol precipitate DNA after TBE electrophoresis before downstream steps.
High background in Western blot (TBS-T) Tween 20 concentration too high; blocking insufficient Use 0.1% Tween 20 (not 0.5%). Increase blocking time to 1 h at RT or overnight at 4°C.
HEPES buffer turns yellow on storage Exposure to light — HEPES photodegradation products Store in amber bottle. Use fresh buffer for critical cell culture experiments.
SSC buffer supports bacterial growth Contamination introduced during handling Filter-sterilize (0.22 µm) after preparation. Add 0.02% sodium azide for long-term storage (note: toxic).
Tris-HCl precipitate forms at 4°C Tris base crystallizes at low temperature when concentrated (>0.5 M) Warm to 37°C and mix. Do not use heat above 50°C.
Osmolality out of range Pipetting error in NaCl or sugar component Re-measure osmolality. ±5% is acceptable. If outside ±10%, discard and prepare fresh.
pH meter calibration errors Electrode aged; calibration buffers expired Calibrate with fresh pH 4.0, 7.0, and 10.0 standards daily. Use temperature compensation at 25°C.

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